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Doctor Doom appears in The Avengers: Earth's Mightiest Heroes, voiced by Lex Lang. He was first mentioned in the episode "The Breakout" (Part 1) during a trade with A.I.M. was made on his behalf. Doctor Doom made his first physical appearance in the second season premiere "The Private War of Doctor Doom" where he sends Lucia von Bardas and an army of Doombots to attack the Avengers Mansion and the Baxter Building which ended with the capture of Invisible Woman and Wasp. Doom had both heroes placed in a special machine as the Avengers and the Fantastic Four make their way towards Latveria. Initially not wanting an international incident with Doctor Doom being the head of a sovereign nation on foreign soil, the Avengers try a stealth attack which Doctor Doom anticipates. Doctor Doom effortlessly defeats both the Avengers and the three remaining Fantastic Four members. Invisible Woman and Wasp are freed only by Doctor Doom's mercy and the machine is destroyed enabling the Avengers and the Fantastic Four to retreat. In the final scene, Doctor Doom was going over the data he had received from the machine where he learns that "Invisible Woman" was actually a Skrull imposter the whole time.[4] In the episode "Infiltration", Doctor Doom returns and hands Iron Man a chip with the ability to scan human beings to see if they are Skrulls or not. He then leaves opting not to take part in the eventual rebellion against the full-scale invasion. In the episode "Emperor Stark", where Doctor Doom was seen battling Thor and Iron Man drones under the Purple Man's control. The outcome of the battle is never stated or shown.

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